Natalia Vodianova is not just a (very) pretty face. Last night the model brought together the crème de la crème of the fashion world for a charity gala to raise funds for the Naked Heart Foundation. There was an incredible line-up of ladies on the red carpet sporting a range of embellished hairpieces, including an ethereal Anne Hathaway with a crystal headband nestled in her tousled up 'do, water-lined eyeliner and a bright red lip as well as Olivia Palermo and Margherita Missoni, both working understated yet glamorous makeup. Last but not least Natalia opted for a Rapunzel-like braid interwoven with sparkling red veil and a pop of red lipstick. Click through for the best beauty looks!